先看效果图：  

引入依赖：

<dependency>
    <groupId>org.apache.poi</groupId>
    <artifactId>poi</artifactId>
    <version>3.13</version>
</dependency>
<dependency>
    <groupId>org.apache.poi</groupId>
    <artifactId>poi-ooxml</artifactId>
    <version>3.13</version>
</dependency>

制作word模板：

1.制作muban.doc,变量用${xx}代替 ,可以根据实际情况调整表格的大小样式等；

 2，将该word另存为muban.xml ，不是修改后缀名哦，我用的wps，如下图  

 打开muban.xml

 修改电子照变量，删除上面的base64字符串（可以先格式化该xml）,修改如下：

分情况：如果是wps转的xml直接把base64替换成成${photo}如下： 

如果是Microsoft Office Word转成的xml需要修改成如下代码，如下： 

<w:binData w:name="wordml://1.jpg">${photo}</w:binData>

 红线框多了，注意节点对称

接下来是循环list的需要修改，直接搜索循环的字段，在外层加上<#list eli as t></#list>包裹即可

 代码如下： 注意节点对称，图片里打错字了，懒得改了

调用导入word的代码即可createword()

说明图片转base64即可，使用的是word模板转成的xml。我是把xml和电子照直接放到webapp里的某文件夹，获取xml路径电子照路径等文件请以实际情况为准。记住变量要和xml里的对应哦

package com.jf.s.util;



import com.jf.s.bean.Education;
import com.jf.s.bean.ProjectExp;
import com.jf.s.bean.Resume;
import com.jf.s.bean.WorkExp;
import com.sun.DateUtil;
import freemarker.template.Configuration;
import freemarker.template.Template;
import sun.misc.BASE64Encoder;

import javax.servlet.http.HttpServletRequest;
import java.io.*;
import java.util.HashMap;
import java.util.List;
import java.util.Map;
import java.util.UUID;

public class ImportWord {

    private Configuration configuration = null;

    public ImportWord(){
        configuration = new Configuration();
        configuration.setDefaultEncoding("UTF-8");
    }


    public String createWord(HttpServletRequest request, Resume r, List<Education> eli,List<WorkExp> wli,List<ProjectExp> pli) throws IOException {
        String path = request.getSession().getServletContext().getRealPath(Sys.Upimg.parentPack);
        String path2 = request.getSession().getServletContext().getRealPath("");


        Map<String,Object> dataMap=new HashMap<String,Object>();
        System.out.println(path2+r.getPhoto());
        dataMap.put("photo",imageToBase64Str(path2+r.getPhoto()));

        dataMap.put("realname",r.getRealname()==null?"未填写":r.getRealname()+"\n\t");
        dataMap.put("sex",r.getSex()==null?"未填写":r.getSex());
        dataMap.put("age",r.getAge()==null?"未填写":r.getAge());
        dataMap.put("birth",r.getBirth()==null?"未填写":r.getBirth());
        dataMap.put("mobile",r.getMobile()==null?"未填写":r.getMobile());
        dataMap.put("email",r.getEmail()==null?"未填写":r.getEmail());
        dataMap.put("education",r.getEducation()==null?"未填写":r.getEducation());
        dataMap.put("schoole",r.getSchool()==null?"未填写":r.getSchool());
        dataMap.put("major",r.getMajor()==null?"未填写":r.getMajor());
        String wage="未填写";
        if(r.getWantWage()!=null){
            if(r.getWantWage().equals("-1"))   wage="面议";
            else  wage=r.getWantWage()+"K";
        }
        dataMap.put("wantWage",wage);
        dataMap.put("wantCity",r.getWantCity()==null?"未填写":r.getWantCity());
        dataMap.put("workTime",r.getWorkTime()==null?"未填写":r.getWorkTime());
        String state="未填写";
        if(r.getState()!=null){
            if(r.getState().equals("1"))   state="在职找工作";
            else  state="已离职";
        }
        dataMap.put("state",state);
        dataMap.put("wantJob",r.getWantJob()==null?"未填写":r.getWantJob());
        dataMap.put("skills",r.getSkills()==null?"未填写":r.getSkills());
        dataMap.put("interest",r.getInterest()==null?"未填写":r.getInterest());
        dataMap.put("certificate",r.getCertificate()==null?"未填写":r.getCertificate());
        dataMap.put("evaluation",r.getEvaluation()==null?"未填写":r.getEvaluation());

        dataMap.put("eli",eli);
        dataMap.put("wli",wli);
        dataMap.put("pli",pli);
        configuration.setDirectoryForTemplateLoading(new File(path));//模板文件所在路径
        Template t=null;
        try {
            t = configuration.getTemplate("resume.xml"); //获取模板文件
        } catch ( Exception e) {
            e.printStackTrace();
        }
        String fn=UUID.randomUUID().toString().replace("-","").substring(0,10)+".doc";
        File outFile = new File(path+"/words/"+fn); //导出文件

        Writer out = null;
        try {
            out = new BufferedWriter(new OutputStreamWriter(new FileOutputStream(outFile)));
        } catch (FileNotFoundException e1) {
            e1.printStackTrace();
        }

        try {
            t.process(dataMap, out); //将填充数据填入模板文件并输出到目标文件
        } catch ( Exception e) {
            e.printStackTrace();
        }
        return Sys.Upimg.parentPack+"/words/"+fn;
    }

    public static String imageToBase64Str(String imgFile) {
        InputStream inputStream = null;
        byte[] data = null;
        try {
            inputStream = new FileInputStream(imgFile);
            data = new byte[inputStream.available()];
            inputStream.read(data);
            inputStream.close();
        } catch (IOException e) {
            e.printStackTrace();
        }
        // 加密
        BASE64Encoder encoder = new BASE64Encoder();
        return encoder.encode(data);
    }
}